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Biophysical Journal 10: 577-583 (1970)
© 1970 the Biophysical Society
ABSTRACT
The expression of free energy change for linear and helical association based on Casper's definition as applied to Oosawa and Kasai's model is described. Redefinition of the thermodynamic quantity
indicates that it is dependent on
fB, the free energy change in the formation of B-bonds, rather than mean distortion energy as previously believed.
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